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Description / Abstract:
INTRODUCTION
To better determine the impacts of using A193 Grade B7 bolts in
stainless steel flanges installed in a Boiler Water Reactor (BWR)
sodium pentaborate (NaPB) systems, quantification of the corrosion
rates of this material in NaPB solutions was investigated. Two
types of tests were performed. First, coupons of 4140 (the base
material for A193 Grade B7), C4340 low alloy steel, C1010 carbon
steel and 410 stainless steel were immersed in a 12% NaPB solution
at ~95°F and a 12 to 20% solution at ~185°F. An A193 Grade B7 bolt
was also immersed in a 12% NaPB solution and in demineralized water
at 95oF. Coupons and bolts were intermittently examined and
photographed, and weight change measurements were made to assess
corrosion rates after three weeks and two months of exposure.
Second, tests to assess corrosion of A193 Grade B7 bolts when
leakage occurs across stainless steel flange seal surfaces were
performed. The test flanges had a 4-inch diameter and a bolt circle
diameter of ~3 inches. Three flanges were exposed at ~99ºF, and one
flange was exposed at ~203ºF. Leakage of the NaPB solution was
simulated by injecting a 12 weight percent NaPB solution through a
small diameter Teflon tube onto one of the four bolts in each
flange at a rate of ~0.1 ml per minute. One flange was allowed to
accumulate borate salts as a result of the leakage. The exterior
surface of the other flange was brushed clean approximately every
two weeks. The third 100ºF flange was insulated with NUKONTM and
was not cleaned during the test period. The 203ºF flange was not
insulated and was allowed to accumulate borate salts over the test
period. Flanges were exposed for approximately two months.
After the nearly two month exposures, the flanges were
disassembled, and the bolts and flanges were photographed and
inspected. The bolts were rinsed of borate salts, weighed,
de-scaled, and reweighed to determine metal loss. Local corrosion
depths were estimated based on the weight losses.
Test methodology is summarized in Section 2. Coupon test results
are summarized in Section 3. Flange bolt testing is summarized in
Section 4.